腐蚀
材料科学
反射损耗
异质结
涂层
微波食品加热
极化(电化学)
铝
复合材料
吸收(声学)
化学工程
复合数
光电子学
化学
物理化学
物理
量子力学
工程类
作者
Qihui Sun,Xiwen He,Baoshan Wu,Hongyan Zhang,Jinyao Li,Nasir Mahmood,Jianan Fu
标识
DOI:10.1016/j.apsusc.2023.157626
摘要
The complexity of the environment leads to corrosion and failure of absorbing functions. The encapsulation and surface modification of multi-gradient structures are typical ways to address this challenge. Herein, a FeCo@C@Al2O3 core–shell heterostructure is developed for the dual functions of absorbing and anti-corrosion using the chemical vapor deposition and hydrolysis of the aluminum sulfate. This unique double-shell structure provides more multiple interface relaxation polarizations, electromagnetic wave scatterings. And the robust carbon layer produces sufficient conduction loss for the FeCo@C@Al2O3. Compared with pure FeCo, the absorption capacity of FeCo@C@Al2O3 increases up to 1.4 times, the minimum reflection loss value achieves −46.7 dB at the thickness of 1.4 mm. And the maximum effective absorption bandwidth is up to 9.3 GHz. While it possesses minimum total RCS value of −13.29 dB∙m2, reflecting the optimal absorbing stealth performance. Besides, the coating Al2O3 layer effectively isolates the diffusion of corrosion ions including Cl-, H2O and O2, the corrosion current and polarization resistance of FeCo@C@Al2O3 are well adjusted to 7.96 × 10-8 A/cm2 and 5.40 × 105 Ω·cm2, respectively. Therefore, the FeCo@C@Al2O3 heterostructure provides an updated platform for the research and development of new absorbing and anti-corrosion materials.
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