Smart SO2 Sensor Based on Cs3Cu2I5@Fe2O3 Nanocrystals for Eliminating Humidity Interference
二氧化硫
化学
有机化学
作者
Yuyan Zhuang,Jintuo Zhu,Danhong Gao,Shuang Gao,Zi‐Jiang Yang,Sheng Huang,Xinjian He
出处
期刊:IEEE Sensors Journal [Institute of Electrical and Electronics Engineers] 日期:2023-12-15卷期号:23 (24): 30504-30515
标识
DOI:10.1109/jsen.2023.3329497
摘要
Sulfur dioxide is a colorless gas with strong pungent odor, and prolonged inhalation can damage the respiratory system and heart. Precise measurement of sulfur dioxide is very important for the human health. While the current sulfur dioxide sensor works at a high temperature and is easily interfered by humidity. Therefore, in this work, we used solution method to coat perovskite nanocrystals Cs 3 Cu 2 I 5 with metal oxides Fe 2 O 3 , and obtained the room-temperature sulfur dioxide gas-sensitive materials Cs 3 Cu 2 I 5 @Fe 2 O 3 nanocrystals. Meanwhile, combined with machine learning, the sensor has the ability of self-calibrating under different humidity environment, realizing the high precision and anti-interference measurement of sulfur dioxide. In addition, in this structure, the coating Fe 2 O 3 not only helps to improve water stability, but also transfer the interaction of sulfur dioxide to the inner Cs 3 Cu 2 I 5 , and lower the gas-sensitive temperature to room temperature. The response/recovery time of the sulfur dioxide sensor based on Cs 3 Cu 2 I 5 @Fe 2 O 3 is 31/816 s, and the sensitivity is 0.19 at 10 ppm. Then, intelligent classification algorithm was used for recognition, and the accurate recognition rate was up to 95.0%. Furthermore, density functional theory was implemented to reveal the gas-sensitive mechanism that sulfur dioxide was adsorbed by Cs 3 Cu 2 I 5 @Fe 2 O 3 nanocrystals, the good response was attributed to the band structure changes significantly, and the hybridization of electron orbitals was appeared between gas and nanocrystals. We believe that the sensor will have potential in sulfur dioxide, and the idea of using machine learning to intelligent eliminate humidity interference can also be extended to other gas sensor.