材料科学
腐蚀
原电池
钛
电偶腐蚀
扫描电子显微镜
合金
介电谱
冶金
极化(电化学)
铆钉
铝
能量色散X射线光谱学
电流密度
复合材料
电化学
化学
电极
物理
物理化学
量子力学
作者
Xinyang Li,Junkai Zhang,Lei Li,Wenjia Wang,Guocheng Xu,Zhong-lin Hou
标识
DOI:10.1002/maco.202414469
摘要
Abstract Using polarization curve scanning, electrochemical impedance spectroscopy, macroscopic morphology observation, scanning electron microscope, X‐ray diffraction (XRD), and energy dispersive spectroscopy (EDS), the corrosion regulars of connectors were investigated. A galvanic corrosion simulation model of aluminum‐titanium rivets was established by electrochemical experimental parameters as boundary conditions. The results showed that the galvanic couple connection accelerated the corrosion significantly. XRD and EDS results show that the main corrosion products are Al 2 O 3, Al(OH) 3 . The corrosion potential of riveted parts decreased from the riveting point to both sides, ranging from −0.664 to −0.655 V. The corrosion current density decreases along both sides, and the corrosion current density at the most edge is 0.0113 A/m 2 . The results of numerical simulation indicate that the model effectively predicted the galvanic corrosion behavior of aluminum‐titanium rivets.
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