腐蚀
材料科学
合金
超临界流体
高熵合金
氧化物
冶金
扩散
晶界
化学工程
微观结构
化学
热力学
物理
工程类
有机化学
作者
Qi Zhao,Xi Huang,Zixiong Zhan,Shanliang Zhou,Junxiong Liu,Pengcheng Zhu,Lihua Wei,Xiaoyan Li,Congyi Li,Yujun Xie
标识
DOI:10.1016/j.corsci.2023.111291
摘要
The effect of alloying elements, Mn, Ti, and Mo, on the corrosion behavior of FeCoNiCr-based high entropy alloy (HEA) in supercritical water was investigated. The corrosion resistance of the HEA was enhanced by adding Mo while reduced with the addition of Ti and Mn. The segregation of Ti and Mo resulted in the formation of oxide films that were both structurally and chemically heterogeneous. Grain boundaries accelerated the diffusion rate of Mn, leading to the formation of MnCr2O4 oxide scales decorated with Mn2O3 particles. In addition, the governing mechanisms of alloying elements on the corrosion behavior of HEAs were also discussed.
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