共聚物
单体
化学
聚合物
硫黄
聚合
高分子化学
硫化物
序列(生物学)
二硫化碳
有机化学
生物化学
作者
Tian‐Jun Yue,Wei‐Min Ren,Xiao‐Bing Lu
出处
期刊:Chemical Reviews
[American Chemical Society]
日期:2023-11-02
卷期号:123 (24): 14038-14083
被引量:1
标识
DOI:10.1021/acs.chemrev.3c00437
摘要
Incorporating sulfur (S) atoms into polymer main chains endows these materials with many attractive features, including a high refractive index, mechanical properties, electrochemical properties, and adhesive ability to heavy metal ions. The copolymerization involving S-containing monomers constitutes a facile method for effectively constructing S-containing polymers with diverse structures, readily tunable sequences, and topological structures. In this review, we describe the recent advances in the synthesis of S-containing polymers via copolymerization or multicomponent polymerization techniques concerning a variety of S-containing monomers, such as dithiols, carbon disulfide, carbonyl sulfide, cyclic thioanhydrides, episulfides and elemental sulfur (S8). Particularly, significant focus is paid to precise control of the main-chain sequence, stereochemistry, and topological structure for achieving high-value applications.
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