Novel vacuum UV/ozone/peroxymonosulfate process for efficient degradation of levofloxacin: Performance evaluation and mechanism insight

Vacuum UV (VUV) irradiation has advantage in coupling oxidants for organics removal because VUV can dissociate water to produce reactive oxygen species (ROS) in situ and decompose oxidants rapidly. In this study, the synergistic activation of peroxymonosulfate (PMS) by VUV and ozone (O3) was explored via developing a novel integrated VUV/O3/PMS process, and the performance and mechanisms of VUV/O3/PMS for levofloxacin (LEV) degradation were investigated systematically. Results indicated that VUV/O3/PMS could effectively degrade LEV, and the degradation rate was 1.67–18.79 times of its sub-processes. Effects of PMS dosage, O3 dosage, solution pH, anions, and natural organic matter on LEV removal by VUV/O3/PMS were also studied. Besides, hydroxyl radical and sulfate radical were main ROS with contributions of 49.7% and 17.4%, respectively. Moreover, the degradation pathways of LEV in VUV/O3/PMS process were speculated based on density functional theory calculation and by-products detection. Furthermore, synergistic reaction mechanisms in VUV/O3/PMS process were proposed. The energy consumption of VUV/O3/PMS decreased by 22.6%− 88.1% compared to its sub-processes. Finally, the integrated VUV/O3/PMS process showed satisfactory results in removing LEV in actual waters, manifesting VUV/O3/PMS had great application potential and feasibility in removing organics in wastewater reuse.