材料科学
离子注入
退火(玻璃)
兴奋剂
接受者
光电子学
薄脆饼
离子
制作
氮化镓
宽禁带半导体
镓
氮化物
分析化学(期刊)
纳米技术
化学
复合材料
冶金
凝聚态物理
医学
有机化学
替代医学
病理
色谱法
物理
图层(电子)
作者
Tetsu Kachi,Tetsuo Narita,Hideki Sakurai,Maciej Matys,Keita Kataoka,Kazufumi Hirukawa,Kensuke Sumida,Masahiro Horita,Nobuyuki Ikarashi,Kacper Sierakowski,Michał Boćkowski,Jun Suda
摘要
P-type doping in selected areas of gallium nitride (GaN) using magnesium (Mg)-ion implantation and subsequent ultra-high-pressure annealing (UHPA) are investigated to improve the performance of vertical GaN power devices. UHPA allows a high-temperature process without decomposition of the GaN surface and virtually complete activation of the implanted Mg ions in GaN. In the present paper, we provide an overview of recent challenges in making UHPA more realistic as an industrial process. Instead of UHPA at more than 1400 °C for a short duration, prolonged UHPA at 1300 °C demonstrates a comparable acceptor activation of Mg-ion-implanted GaN. This can reduce the annealing pressure to approximately 300 MPa and enlarge the processable wafer diameter. The second challenge is controlling the doping profiles in the lateral and vertical directions. We demonstrate fine patterning of the p-type regions, which indicates the limited lateral diffusion of Mg through UHPA. However, controlling the vertical doping profile is challenging. The nitrogen vacancies formed by ion implantation reduce the effective acceptor concentration near the surface, which can be compensated for by sequential nitrogen ion implantation. Defect-assisted Mg diffusion to the deeper region causes a redistribution of the Mg atoms and should be considered in the design of a device. Such anisotropic diffusion of Mg to the c-axis has potential applications in the fabrication of unique vertical device structures such as super junctions.
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