电致变色
材料科学
聚酰胺
电化学
光电子学
透射率
单体
光化学
化学工程
电极
聚合物
高分子化学
化学
复合材料
工程类
物理化学
作者
Dongxu Li,Xiaohong Wang,Juguo Dai,Hao Líu,Yiting Xu,Conghui Yuan,Guorong Chen,Lizong Dai
标识
DOI:10.1016/j.snb.2023.134161
摘要
A new triarylamine-based polyamide was synthesized from 1,4-cyclohexanedicarboxylic acid and diamine monomer containing adamantane group (PA-CA), which exhibits high fluorescence quantum up to 46.1% and excellent electrochromic behaviors. The photoluminescence of PA-CA was quenched by coordination and internal filtration effect to realize Fe3+ response. Neutral colorless PA-CA film was converted to the oxidized blue in the electrochemical oxidation process and the maximum transmittance reached 80%, and the transmittance still exceeded 55% after 10,000 s. A Sandwich structure electrochromic device with PA-CA as the active layer was constructed with a simple strategy and different contents were displayed through patterned customization. Electrofluorochromic performance was regulated and decoding information was customized by applying voltage changes of the light and dark for PA-CA film. The applications of multifunctional integrated PA-CA responding to stimulus have broad prospects in the field of Fe3+ fluorescence sensors, photodetectors and multicolor electrochromic display devices.
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