Conventional Non‐Fluorescent Polymers: Unconventional Security Inks for Data Storage and Multidimensional Photonic Cryptography

Abstract Traditional security inks relying on fluorescent/phosphorescent molecules are facing increasing risks of forgery or tampering due to their simple readout scheme (i.e., UV‐light irradiation) and the advancement of counterfeiting technologies. In this work, a multidimensional data‐encryption method based on non‐fluorescent polymers via a “lock–key” mechanism is developed. The non‐fluorescent invisible polymer inks serve as the “lock” for data‐encryption, while the anti‐rigidochromic fluorophores that can distinctively light up the polymer inks with programed emissions are “keys” for decryption. The emission of decrypted data is prescribed by polymer chemical structure, molecular weight, topology, copolymer sequence, and phase structure, and shows distinct intensity, wavelength, and chirality compared with the intrinsic emission of fluorophores. Therefore, the data is triply encrypted and naturally gains a high‐security level, e.g., only one out of 20 000 keys can access the only correct readout from 40 000 000 possible outputs in a three‐polymers‐based data‐encryption matrix. Note that fluorophores lacking anti‐rigidochrimism cannot selectively light up the inks and fail in data‐decryption. Further, the diverse topologies, less well‐defined structures, and random‐coiled shapes of polymers make it impossible for them to be imitated. This work offers a new design for security inks and boosts data security levels beyond the reach of conventional fluorescent inks.