Study on optimization and performance of biological enhanced activated sludge process for pharmaceutical wastewater treatment

Simulated pharmaceutical wastewater was treated by moving bed biofilm reactor (MBBR) and total reflux sludge reactor process (STR) system. By cultivating specific bacterial groups, optimizing reactor process parameters, and comparatively analyzing the pollutant removal efficiency under stable operating conditions of the system, the treatment efficiency of the two systems under the combined impact load of organic pollutants on the target pollutants indole and naphthalene was studied. The optimal operation parameters of reactors: hydraulic retention time (HRT) was 8 h, aeration was 0.12 m3/h. The effect was better in 25 ± 1 °C than that in 20 ± 2 °C. During stable operation, the average removal rate of chemical oxygen demand (COD) and ammonia nitrogen (NH4+-N) of the MBBR system was significantly higher than that of STR, and the two kinds of target pollutants concentration in water was lower than the detection limit. In the combined impact test of organic pollutants, the dominant bacterial group obtained by domestication had a high degradation ability, so the combined impact of indole and naphthalene had little effect on the two reactors. But in the fourth stage, the residual naphthalene concentration in the STR system effluent exceeded the target value. Therefore, the MBBR process has a stronger treatment effect on pharmaceutical wastewater than the STR system during the stable period and the impact load stage.