光催化
材料科学
可见光谱
红外线的
紫外线
光化学
X射线光电子能谱
氢
纳米颗粒
辐照
化学工程
纳米技术
化学
光电子学
催化作用
光学
有机化学
物理
工程类
核物理学
作者
Xiaojie Li,Jingkai Lin,Jiaquan Li,Huayang Zhang,Xiaoguang Duan,Hongqi Sun,Yingping Huang,Yanfen Fang,Shaobin Wang
出处
期刊:ACS Sustainable Chemistry & Engineering
[American Chemical Society]
日期:2021-04-23
卷期号:9 (21): 7277-7285
被引量:23
标识
DOI:10.1021/acssuschemeng.1c01262
摘要
In this work, solar-heating-induced temperature-based photocatalytic hydrogen evolution reaction (PC-HER) of different photocatalysts (TiO2 P25, g-C3N4, and their loaded Pt) was comprehensively studied and analyzed with the assistance of a series of temperature-based in situ characterizations. It was found that pristine TiO2 P25 and g-C3N4 displayed enhanced PC-HER performances with increasing temperature (25–65 °C), while their loaded Pt nanoparticles (NPs) demonstrated a different behavior under ultraviolet (UV) or visible irradiation, presenting the highest hydrogen evolution rate at 35 °C. More interestingly, Pt NPs-g-C3N4 showed increasing PC-HER performances from 25 to 65 °C under visible light irradiation. Characterizations suggested that lowered electrical impedance, reduced band gap, increased light absorption, and elongated photoelectron lifetime with increased temperature are beneficial for improved PC-HER. However, agglomeration of Pt NPs significantly deteriorated the PC-HER performance at higher temperature and UV light can aggravate the thermal agglomeration of Pt NPs.
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