材料科学
法拉第效率
电化学
阳极
水溶液
化学工程
电极
电解质
锐钛矿
极化(电化学)
无机化学
有机化学
催化作用
化学
物理化学
工程类
光催化
作者
Liming Ling,Ying Bai,Zhaohua Wang,Qiao Ni,Guanghai Chen,Zhiming Zhou,Chuan Wu
标识
DOI:10.1021/acsami.7b17659
摘要
Sodium alginate (SA) is investigated as the aqueous binder to fabricate high-performance, low-cost, environmentally friendly, and durable TiO2 anodes in sodium-ion batteries (SIBs) for the first time. Compared to the conventional polyvinylidene difluoride (PVDF) binder, electrodes using SA as the binder exhibit significant promotion of electrochemical performances. The initial Coulombic efficiency is as high as 62% at 0.1 C. A remarkable capacity of 180 mAh g-1 is achieved with no decay after 500 cycles at 1 C. Even at 10 C (3.4 A g-1), it remains 82 mAh g-1 after 3600 cycles with approximate 100% Coulombic efficiency. TiO2 electrodes with SA binder display less electrolyte decomposition, fewer side reactions, high electrochemistry reaction activity, effective suppression of polarization, and good electrode morphology, which is ascribed to the rich carboxylic groups, high Young's modulus, and good electrochemical stability of SA binder.
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