齿合度
铑
催化作用
化学
磷
不对称氢化
有机化学
组合化学
药物化学
对映选择合成
晶体结构
作者
Yu Fu,Jian‐Hua Xie,Aiguo Hu,Hai Zhou,Lixin Wang,Qi‐Lin Zhou
摘要
Novel monodentate phosphorus ligands containing the 1,1′-spirobiindane backbone have been synthesized and applied in the asymmetric rhodium-catalyzed hydrogenation of functionalized olefins, providing excellent enantioselectivities (up to 99.3% ee).
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