催化作用
氮气
介孔材料
介孔二氧化硅
乙二胺
材料科学
氮化物
纳米颗粒
金属
碳纤维
芳基
酯交换
氮化碳
化学工程
纳米技术
化学
有机化学
复合数
复合材料
工程类
图层(电子)
烷基
光催化
作者
Xin Jin,Veerappan V. Balasubramanian,Sakthivel Tamil Selvan,Dhanashri P. Sawant,M. Adharvana Chari,Gao Qing Lu,Ajayan Vinu
标识
DOI:10.1002/anie.200903674
摘要
Nitrogen-rich carbon nitride is obtained as ultrasmall, discrete, mesoporous nanoparticles (see picture) by reaction of ethylenediamine with CCl4 in the nanochannels of a mesoporous silica template. Its high nitrogen content, large surface area, and large pore volume make it a highly active catalyst for transesterification of β-keto esters of aryl, aliphatic, and cyclic primary alcohols. Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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