Improving Mechanical Strength and Water Barrier Properties of Pulp Molded Product by Wet-End Added Polyamide Epichlorohydrin/Cationic Starch

As desirable food packaging materials, pulp molded products have attracted great attention from both academia and industry. To endow the products with high mechanical strength and water barrier properties by low-cost wet-end additives to broaden their application fields, polyamide epichlorohydrin (PAE) or/and cationic starch (CS) were added to the pulp slurry after the addition of oil- and water-proof agents. Results showed that the optimal pulp molded product was obtained at a PAE and CS content of 1.0 and 0.6%, respectively. The resulting product had a dry strength of 24.4 kN/m, a wet strength of 4.22 kN/m, and a water absorption of 51.5%. The addition of CS was beneficial to the properties of the PAE wet-end added product due to the formation of hydrogen bonding with cellulose fibers and PAE, which also led to a decreased PAE dosage for health concern as food packaging materials. Finally, the PAE/CS wet-end added pulp molded product was applied for orange fresh-keeping in the fridge. The product displayed much more shape stability and lower weight increase in comparison with that of the product without the addition of PAE and CS. This indicated the great application prospects of our designed pulp molded product as a fruit freprospectssh-keeping packaging material.