Enhanced luminescence properties and device applications of Tb3+-doped Cs4PbBr6 perovskite quantum dot glass

Cs 4 PbBr 6 perovskite quantum dots (QDs) have unique optoelectronic properties and are expected to become a new generation of luminescent materials. However, poor stability, low photoluminescence quantum yield (PLQY), and poor understanding as to the origin of photoluminescence behavior limit its further application. In this study, a series of Tb 3+ -doped Cs 4 PbBr 6 perovskite QD glasses with excellent stability were obtained through the optimization of Tb 3+ doping concentration and in-situ crystallization temperature. Density functional theory calculations and experimental characterization showed that an appropriate amount of lattice-incorporated Tb 3+ ions can reduce structural defects in QDs, improve the PLQY, and reduce the QD heavy-metal requirements. Notably, the maximum PLQY value reached 47%, which is near to the Cs 4 PbBr 6 perovskite crystal. Furthermore, a high-performance white light-emitting diode (WLED) device was prepared. The device featured a color rendering index of 80 and luminous efficiency of 41 lm W −1 . Finally, a QD glass with double emission peaks was prepared by controlling the in-situ crystallization temperature (550 °C). The temperature sensitivity of the QD glass was then studied using the fluorescence intensity ratio method. The maximum relative temperature sensitivity (Sr) reached 2.03% K −1 , which is higher than the previously reported value. Thus, the method proposed in this study can greatly improve the photoluminescence properties of Cs 4 PbBr 6 QD glass and expand its applications in WLED and visual temperature sensing.