钙钛矿(结构)
锡
材料科学
光电子学
工程物理
化学
物理
冶金
结晶学
作者
Yujia Guo,Huanhuan Yao,M.L. Yin,Miao Zhang,Feng Hao
标识
DOI:10.1002/solr.202400121
摘要
Recently, the emerging of low‐dimensional tin perovskite solar cells (TPSCs) by introducing bulky organic spacers has attracted extensive attention. It can not only inhibit the oxidation of Sn 2+ , but also reduce the ion migration and self‐doping effect. Thanks to these advantages, the TPSCs have achieved an impressive power conversion efficiency (PCE) of over 15% recently. However, the introduction of organic spacers will impede the carrier transport and thus limit the attainable PCE. Therefore, it is important to understand the carrier transport mechanism in low‐dimensional perovskite to develop more efficient and stable TPSCs. In this review, the latest progress of carrier transport in low‐dimensional TPSCs is summarized in detail. Firstly, we discuss the characteristics of carrier transport in low‐dimensional tin perovskites. Then, the strategies to improve carrier transport are discussed, mainly from the aspects of crystal orientation, crystallization kinetics, defects, interface energy level alignment, quantum well effect and exciton binding energy. Finally, the future challenges and prospects are expounded in order to prepare high‐performance and stable low‐dimensional TPSCs. This article is protected by copyright. All rights reserved.
科研通智能强力驱动
Strongly Powered by AbleSci AI