材料科学
晶粒生长
晶界
粒度
钛酸钡
铁电性
晶界扩散系数
陶瓷
晶界强化
凝聚态物理
居里温度
矫顽力
微晶
极化(电化学)
铁电陶瓷
电介质
化学物理
矿物学
复合材料
微观结构
冶金
光电子学
化学
铁磁性
物理
物理化学
作者
Hong Li,Bo Wu,Cong Lin,Xiao Wu,Tengfei Lin,Min Gao,Hong Tao,Wenjuan Wu,Chunlin Zhao
标识
DOI:10.1016/j.jmst.2023.04.036
摘要
Barium titanate [BaTiO3 (BT)]-based ceramics are typical ferroelectric materials. Here, the discontinuous grain growth (DGG) and relevant grain size effect are deeply studied. An obvious DGG phenomenon is observed in a paradigmatic Zr4+-doped BT-based ceramic, with grains growing from ∼2.2–6.6 to ∼121.8–198.4 μm discontinuously near 1320 ℃. It is found that fine grains can get together and grow into large ones with liquid phase surrounding them above eutectic temperature. Then the grain boundary density (Dg) is quantitatively studied and shows a first-order reciprocal relationship with grain size, and the grain size effect is dependent on Dg. Fine grains lead to high Dg, and then cause fine domains and pseudocubic-like phase structure because of the interrupted long-range ferroelectric orders by grain boundary. High Dg also causes the diffusion phase transition and low Curie dielectric peak due to the distribution of phase transition temperature induced by internal stress. Local domain switching experiments reveal that the polarization orientation is more difficult near the grain boundary, implying that the grain boundary inhibition dominates the process of polarization orientation in fine-grain ceramics, which leads to low polarization but a high coercive field. However, large-grain ceramics exhibit easy domain switching and high & similar ferroelectricity. This work reveals that the grain boundary effect dominates the grain size effect in fine-grain ceramics, and expands current knowledge on DGG and grain size effect in polycrystalline materials.
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