Typical Tire Additives in River Water: Leaching, Transformation, and Environmental Risk Assessment

Tire wear particles (TWPs) released during vehicle driving can enter water bodies, leading to leaching of tire additives (TAs) in aquatic environments. However, the transformation behavior and related ecological impacts of TAs and their transformation products (TPs) remain unclear. In this study, laboratory-based simulation experiments and field investigations were conducted to explore the transformation mechanisms and ecological risks of TAs. After being placed in river water for 24 h, about 7-95% of 12 investigated TAs in TWPs were leached. Forty-eight TPs from eight TAs were tentatively identified along with different transformation pathways via suspect screening by high-resolution mass spectrometry. Semiquantitative results indicated that TPs derived from N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylene-diamine (6PPD) were predominant in leachates, while aryl hydrolysis and quinone pathways were the main transformation pathways. Field investigations on urban surface water samples from 16 sites in Hong Kong revealed the occurrence of 17 TAs and 1 TP, with concentrations ranging from 13.9 to 2230 ng/L (median ± standard deviation: 226 ± 534 ng/L). Sixteen TPs from six TAs were additionally identified via suspect screening. It is estimated that 6PPD-quinone and seven TAs could pose medium to high ecological risk, while N-(1,3-dimethylbutyl)-N'-phenyl-p-quinonediimine, a frequently detected TP, was identified as a persistent-bioaccumulative-toxic substance.