化学
溶剂
焓
吉布斯自由能
电子供体
二氯乙烷
比例(比率)
热力学
物理化学
计算化学
电子
溶剂效应
有机化学
量子力学
物理
催化作用
摘要
The effectivity of solvents as electron pair donors, their donicity as expressed by their donor numbers DN, is reexamined. The linear dependence of the enthalpy and the Gibbs free energy for the reaction of donor solvents with antimony pentachloride is affirmed. Extension of the DN scale by other measured quantities, via their linear correlations for sets of solvents where both kinds of data are known is applied to Drago's E-C scale, Kamlet's β scale, and Koppel's B scale. This extension, added to previous extensions employing Selbin's DI, II and Popov's δ23Na, produces a DN scale for 170 solvents. The relation of DN measured for isolated solvent molecules in 1,2-dichloroethane to DN values measured for bulk solvents is examined by means of the scaled particle theory and solute-solvent interaction terms. A scale of normalized donor numbers DN
N
is presented. These values are practically the same as the β scale, and for those solvents for which DN values are presented here and β values are lacking, they can serve in their place for those preferring to use the β scale for donor solvents.
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