材料科学
氧化锡
纳米颗粒
化学工程
纳米技术
化学气相沉积
多孔性
二氧化锡
气体扩散
微型多孔材料
氧化物
复合材料
工程类
冶金
燃料电池
作者
Carlos Martínez,B. J. Hockey,Christopher B. Montgomery,Steve Semancik
出处
期刊:Langmuir
[American Chemical Society]
日期:2005-07-19
卷期号:21 (17): 7937-7944
被引量:238
摘要
We have sought to enhance the sensitivity of conductometric gas microsensors through the design and fabrication of porous, three-dimensional tin oxide nanoparticle structures. Electrostatically controlled layer-by-layer processing in aqueous solutions was used to decorate sacrificial latex microspheres with Sb:SnO2 nanoparticles. To evaluate their sensing performance, these structures were then deposited as films, via micropipetting, on MEMS micro-hot-plate platforms with interdigitated electrodes. Prior to gas testing, rapid heating of the micro-hot-plates was used to remove the sacrificial latex templates, thereby revealing a 3-D structure composed of interconnected spherical tin oxide nanoparticle shells with porous ultrathin walls. Changes in film conductance, caused by exposure to test gases (methanol, carbon monoxide, benzene, water) in a dry air background, were measured at different temperatures. Hollow nanoparticle microsphere films exhibited partial selectivity for these different gases, good dynamic range at different temperatures and gas concentrations, and good repeatability and stability over long runs. These films also yielded approximately 3-fold and 5-fold increases in sensitivity to methanol when compared to SnO2 polycrystalline chemical vapor deposition films and Sb:SnO2 microporous nanoparticle films, respectively. Gains in sensitivity are attributed to the multiscale porous architecture of the hollow microsphere films. This architecture promotes gas diffusion and increases the active surface area.
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