灵霉素
致幻剂
化学
蘑菇
立体化学
生物
食品科学
药理学
作者
Osamu Shirota,Wataru Hakamata,Yukihiro Goda
摘要
The concise large-scale syntheses of psilocin (1) and psilocybin (2), the principal hallucinogenic constituents of "magic mushroom", were achieved without chromatographic purification. The key step in the synthesis of 2 was the isolation of the dibenzyl-protected intermediate (7) as a zwitterionic derivative (8), which was completely identified by means of 2D NMR analyses.
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