Three‐Dimensional MoS2@CNT/RGO Network Composites for High‐Performance Flexible Supercapacitors

Abstract Two‐dimensional atomically thick materials, reduced graphene oxide (RGO), and layered molybdenum disulfide (MoS 2 ) have been investigated as potential novel energy storage materials because of their distinct physicochemical properties. These materials suffer, however, from rapid capacity decay and low rate capability. This study describes a facile, binder‐free approach to fabricate large‐scale, 3D network structured MoS 2 @carbon nanotube (CNT)/RGO composites for application in flexible supercapacitor devices. The as‐obtained composites possess a hierarchical porosity, and an interconnected framework. The electrochemical supercapacitive measurements of the MoS 2 @CNT/RGO electrode show a high specific capacitance of 129 mF cm −2 at 0.1 mA cm −2 . The symmetric supercapacitor devices based on the as‐obtained composites exhibit a long lifetime (94.7 % capacitance retention after 10 000 cycles), and a high electrochemical performance (29.7 mF cm −2 ). The present experimental findings will lead to scalable, binder‐free synthesis of MoS 2 @CNT/RGO hybrid electrodes, with enhanced, flexible, supercapacitive performance, in portable and wearable energy storage devices.