轮烷
化学
环加成
分子内力
小提琴手
电子转移
哑铃
烷基
高分子化学
结晶学
分子
光化学
立体化学
超分子化学
有机化学
催化作用
医学
物理疗法
作者
Hui Wang,Zhijun Zhang,Heng‐Yi Zhang,Yu Liu
标识
DOI:10.1016/j.cclet.2013.04.007
摘要
A [3]rotaxane 1 involving two naphtho-21-crown-7 (N21C7) rings and a dumbbell-shaped component 4 was synthesized. The dumbbell-shape molecule 4 contains one viologen nucleus, two secondary alkyl ammonium sites and two phenyl stoppers. After threading the N21C7 ring with the thread-like ammonium guest 3, the copper(I)-catalyzed Huisgen alkyne-azide 1,3-dipolar cycloaddition (CuAAC “click” reaction), was performed to connect the pseudorotaxanes with viologen unit 2 and generate 1. Through treating the [3]rotaxane by the base and acid circularly, the two N21C7 rings can make shuttling motion along the axle. Meanwhile the distance between the electron-deficient viologen unit and the electron-rich naphthol group can be adjusted precisely along with a remarkable intramolecular charge-transfer (CT) behavior.
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