沸石
结晶度
热液循环
吸附
化学工程
煤
原位
材料科学
水热合成
矿物学
相(物质)
煤矿开采
化学
催化作用
有机化学
复合材料
工程类
作者
XinmeiLiu,ZifengYan,HuaipingWang,YantuoLuo
出处
期刊:天然气化学杂志:英文版
日期:2003-01-01
卷期号:12 (1): 63-70
被引量:21
摘要
NaY zeolites were in-situ synthesized from coal-based kaolin via the hydrothermal method.The effects of various factors on the structure of the samples were extensively investigated. The sampleswere characterized by N2 adsorption, XRD, IR and DTG-DTA methods, and the results show that thecrystallization temperature and amount of added water play an important role in the formation of the zeo-lite structure. The 4A and P zeolites are the competitive phase present in the resulting product. However,NaY zeolites with a higher relative crystallinity, excluding impure crystals and the well hydrothermal sta-bility, can be synthesized from coal-based kaolin. These zeolites possess a larger surface area and a narrowpore size distribution, and this means that optimization of this process might result in a commercial routeto synthesize NaY zeolites from coal-based kaolin.
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