光催化
X射线光电子能谱
铋
漫反射红外傅里叶变换
材料科学
介电谱
光电流
扫描电子显微镜
化学工程
透射电子显微镜
核化学
催化作用
分析化学(期刊)
电化学
化学
纳米技术
有机化学
物理化学
光电子学
工程类
复合材料
冶金
电极
作者
Yang Bai,Liqun Ye,Ting Chen,Pingquan Wang,Li Wang,Xian Shi,Po Keung Wong
标识
DOI:10.1016/j.apcatb.2016.10.066
摘要
Bismuth oxyhalides (BiOX, X = Br, I) photocatalysts are rarely applied for photocatalytic reduction reaction withthe photo-induced electron, as this is impeded by their low conduction band. As a widely used approach for enhancing the photocatalytic reduction activity, bismuth-rich strategy results the bismuth content of BiOX photocatalysts increasing. In this paper, a solid solutions of bismuth-rich Bi4O5BrxI2-x were prepared applying the molecular precursor method. Bi4O5BrxI2-x were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), element mapping, Brunauer–Emmett–Teller surface analysis (BET), UV–vis diffuse reflectance spectroscopy (DRS), and X-ray photoelectron spectroscopy (XPS). The obtained photocatalytic data showed that Bi4O5BrxI2-x solid solutions had higher photocatalytic activities than Bi4O5Br2 and Bi4O5I2. At an optimal ratio of x = 1, the Bi4O5BrI photocatalyst showed the highest photocatalytic reduction activity for CO2 conversion (22.85 μmol h−1 g−1 CO generation, AQE was 0.372 at 400 nm) and Cr(VI) removal (88%). CO2 adsorption data and CO2 temperature programmed desorption (CO2-TPD) revealed that Bi4O5BrI exhibited the highest chemical adsorption ability of CO2 molecules Photocurrent and electrochemical impedance (EIS) spectroscopy demonstrated the enhanced photo-induced carrier separation efficiency of Bi4O5BrI. These mechanistic studies suggest that Bi4O5BrxI2-x solid solutions are excellent photocatalysts for solar fuel generation and environmental remediation.
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