白磷
催化作用
磷
环境友好型
光催化
白光
组合化学
构造(python库)
危险废物
化学
过程(计算)
光催化
纳米技术
有机化学
工艺工程
材料科学
计算机科学
废物管理
光电子学
工程类
生态学
操作系统
生物
程序设计语言
作者
Changlin Yu,Wei Liu,Xinlei Huangfu,Junnian Wei,Jiangxi Yu,Wen‐Xiong Zhang
标识
DOI:10.1002/chem.202302289
摘要
Abstract Organophosphorus compounds (OPCs) are widely used in many fields. However, traditional synthetic routes in the industry usually involve multistep and hazardous procedures. Therefore, it's of great significance to construct such compounds in an environmentally‐friendly and facile way. Herein, a photoredox catalytic method has been developed to construct novel phosphoryltriacetates. Using fac ‐Ir(ppy) 3 (ppy=2‐phenylpyridine) as the photocatalyst and blue LEDs (456 nm) as the light source, white phosphorus can react with α ‐bromo esters smoothly to generate phosphoryltriacetates in moderate to good yields. This one‐step approach features mild reaction conditions and simple operational process without chlorination.
科研通智能强力驱动
Strongly Powered by AbleSci AI