超级电容器
材料科学
循环伏安法
纳米复合材料
离子液体
石墨烯
介电谱
热重分析
钨酸盐
电容
氧化物
化学工程
傅里叶变换红外光谱
电极
电化学
纳米技术
化学
有机化学
冶金
工程类
物理化学
催化作用
作者
Samad Dalvand,Zahra Khoushab,S. Morteza Mousavi–Khoshdel,Hossein Ghafuri,Hamid Reza Esmaili Zand,Mehran Omidvar
标识
DOI:10.1016/j.ijhydene.2022.12.026
摘要
In this study, using Fe3O4, graphene oxide (GO), Na2WO4, and ionic liquid (IL), [email protected] Fe3O4-IL-W as a novel nanocomposite has been synthesized to obtain a high-performance supercapacitor. The morphologies and structures of materials have been characterized by Fourier-transform infrared (FT-IR) spectroscopy, thermal gravimetric analysis (TGA), X-ray diffraction (XRD), vibrating-sample magnetometer (VSM), scanning electron microscopy (FESEM), and energy diffraction X-ray (EDX) analysis. The behavior of electrochemical and supercapacitive nanocomposite has been investigated using cyclic voltammetry (CV), galvanostatic charge/discharge (GCD), and electrochemical impedance spectroscopy (EIS). The fabricated electrode material exhibited high specific capacitance (332.45 F/g at 0.2 A/g) and excellent electrochemical performance based on the cyclic stability (capacitance retention of 91.3% after 10,000 cycles). Furthermore, a symmetric supercapacitor device based on [email protected] Fe3O4-IL-W was successfully assembled and an energy density of 7.38 Wh/kg at a power density of 40 W/kg has been obtained. Consequently, the [email protected] Fe3O4-IL-W nanocomposite electrode material is expected to be a promising material for supercapacitor applications and other energy devices.
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