润滑油
润滑性
离子液体
相容性(地球化学)
摩擦学
材料科学
边界润滑
润滑
吸附
摩擦系数
钼
摩擦改进剂
长链
化学工程
复合材料
化学
有机化学
冶金
催化作用
高分子科学
工程类
作者
Yong Shi,Shu Yuan Yang,Xia Zhang,Weimin Liu
出处
期刊:Soft Matter
[The Royal Society of Chemistry]
日期:2024-01-01
卷期号:20 (2): 365-374
摘要
Anti-wear (AW) additives and friction modifiers (FMs) and their interactions in lubricants are critical to tribological performance. This research investigates the compatibility and synergism of three oil-soluble alkylamine-phosphate ionic liquids with friction modifiers, organomolybdenum compounds. Three proton-based ionic liquids (PILs) were synthesized using a simple, low-cost, and unadulterated procedure as well as the chain lengths of the PILs affected the effectiveness of friction reduction and anti-wear. For example, the effect of a short-chain PIL alone as an additive on friction and wear behavior was not significant, whereas a long-chain PIL was more effective. In addition, PILs appeared to be able to coexist with organic molybdenum compounds and worked synergistically with dialkyl dithiophosphate oxygen molybdenum (MoDDP) to produce a sustained low coefficient of boundary friction (the coefficient of friction approaching 0.042). We proposed a three-stage tribochemical process to explain this interaction of PILs + MoDDP with contact surfaces to form physically adsorbed friction-reducing films and chemically reactive wear-protective films. This study reveals the compatibility and synergistic effects of two common lubricant components, which can be used to guide lubricant development in the future.
科研通智能强力驱动
Strongly Powered by AbleSci AI