氧还原
纳米颗粒
氧还原反应
碳纤维
氧气
电催化剂
材料科学
还原(数学)
化学
化学工程
纳米技术
电化学
电极
物理化学
复合材料
有机化学
工程类
复合数
数学
几何学
作者
Haiyan Du,Feifei Ding,Lin Gu,Xianxi Zhang,Konggang Qu,Yun‐Wu Li,Tianyan Lan,Li Jin,Yan Zhang,Qingzhou Yao,Weiyu Lu
标识
DOI:10.1016/j.jallcom.2021.161174
摘要
A series of CoO/Co/N-C catalysts are synthesized by the self-polymerization of dopamine in the presence of Co2+ followed by subsequent calcination. The optimized CoO/Co/N-C-10–700 catalyst possesses a large surface area (339.18 m2 g−1), a micro-mesoporous structure and abundant active sites. The nitrogen doped carbon layers can not only avoid the leakage of catalytic sites from the matrix, but also reduce the interparticle resistance for electronic and ionic transportation. Co-N-C, acting as the main active sites, contributes much to the good oxygen reduction reactivity (ORR). CoO/Co nanoparticles can enhance the conductivity of the material and are favorable for the reduction or disproportionation of peroxide species. The synergetic effect between them can efficiently boost the charge transfer ability and provide more active sites. The CoO/Co/N-C-10–700 catalyst displays a high onset potential (0.97 V vs. RHE), a large limiting current density (4.0 mA cm−2 at 0.04 V vs. RHE) and a good cycling stability. This investigation opens a new window to design low cost ORR catalyst with high catalytic activity.
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