电致发光
钙钛矿(结构)
材料科学
光致发光
光电子学
发光二极管
二极管
量子效率
发光
化学工程
图层(电子)
纳米技术
工程类
作者
Yuhang Zhou,Yanhui Lou,Xueqi Wang,Kaili Wang,Jing Chen,Chun‐Hao Chen,Zhao-Kui Wang
标识
DOI:10.1002/adom.202101655
摘要
Abstract Compared with red and green perovskite light‐emitting diodes (PeLEDs), blue PeLEDs are still unable to well control spectral stability due to the issues of ion migration and phase separation under external operating conditions. Herein, a strategy using organometallic ligands is reported to achieve spectrally stable PeLEDs. The obtained perovskite film exhibits stable photoluminescence spectra under UV excitation (365nm) and continuous heating of 70 °C. The device delivers an external quantum efficiency (EQE) of 6.7% with 50% lifetime ( T 50 ) of 21.6 min. Under high driving voltage (from 2 to 7.5 V), no obvious spectral shift has occurred for the electroluminescence spectrum at 481 nm. This work confirms the positive effect of organometallic ligands in quasi‐2D perovskite and provides a new idea for proposing effective ligands to act on the perovskite luminescence layer in the future.
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