脱氢
纳米棒
X射线光电子能谱
高分辨率透射电子显微镜
材料科学
催化作用
丙烷
拉曼光谱
退火(玻璃)
化学工程
选择性
纳米结构
纳米技术
化学
有机化学
透射电子显微镜
冶金
工程类
物理
光学
作者
Chun‐Jiang Jia,Feng Luo,Rui Liu,Ling‐Dong Sun,Chun‐Hua Yan
标识
DOI:10.1016/j.materresbull.2012.12.006
摘要
CeVO4 hollow sphere nanostructures have been prepared by a simple hydrothermal synthesis method. HRTEM investigation indicates that the CeVO4 hollow spheres are assembled by small single crystal nanorods. Through a plus post annealing treatment at 500 °C, the CeVO4 hollow spheres have more Ce4+ species (Ce4+/(Ce4+ + Ce3+) is ca. 5%) in the surface compared with the as-prepared sample (ca. 1%) based on the XPS results. No CeO2 and V2O5 phases were examined by both XRD and Raman spectroscopy, which indicates that Ce3+–Ce4+/V5+–V4+ coexist in the annealed CeVO4 hollow spheres, confirmed by the existence of V4+ detected by XPS. At 500 °C, the nanorods assembled CeVO4 hollow spheres exhibits a rather very high selectivity (ca. 70%) for propylene in oxidative dehydrogenation (ODH) reaction of propane. The presence of Ce4+, which induces additional V4+ in these hollow sphere nanostructures, is critical for the enhancement of selectivity of the catalyst.
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