Heat treatment is one of the most effective controlling factors used to improve the thermal conductivity (TC) of any alloy castings. In this work, the microstructure of the Al-7Si binary alloy modified by heat treatment at 520 °C for 1−48 h was reported. Both size and shape of the eutectic Si particles are affected by the heat treatment process. Optical microscopy (OM), scanning electron microscopy (SEM) and X-Ray diffraction (XRD) analysis were carried out to characterize the eutectic Si phase transformation. The acicular-shaped eutectic `Si particles were broken into smaller segments and gradually spheroidized. The TC of the alloy heat treated for 12 h increases by 10.5% compared to the as-cast alloy. The correlation between the TC performance and the morphology of eutectic Si phases is detailed discussed.