热解
催化作用
液化
水热液化
热解油
生物燃料
化学
有机化学
柴油
生物能源
制浆造纸工业
废物管理
工程类
作者
Yufu Xu,Yuanhua Hu,Yubin Peng,Lulu Yao,Yinghui Dong,Baocheng Yang,Ruhong Song
标识
DOI:10.1016/j.biortech.2019.122665
摘要
Microalgae bio-oil production is related to the sustainable use of world energy in the future. In the present work, catalytic pyrolysis and liquefaction behavior of microalgae for bio-oil production were investigated. The results show that the rare earth compounds as catalysts contributed to significantly accelerating the pyrolysis of microalgae via reducing the activation energy of pyrolysis process. Ce(II)/HZSM-5 presented the optimal catalytic pyrolysis and liquefaction effects by helping cut the microalgae molecule chains. The maximum bio-oil yield amounted to 49.71 wt% at the catalyst concentration of 5 wt%. The chemical components of the Spirulina bio-oil were composed of carboxylic acids, ketones, olefins, amides, ethers, esters, and partially cyclic N-containing compounds. Although the combustion performances of the Spirulina bio-oil are worse than those of the diesel fuel, it is superior to the reported rice husk bio-oil, suggesting a promising potential application prospect.
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