去湿
润湿
纳米尺度
分子动力学
粘附
材料科学
表面能
润湿转变
花瓣
亚稳态
纳米技术
化学物理
复合材料
化学
计算化学
植物
有机化学
生物
作者
Jinwei Shao,Yinguo Huang,Meirong Zhao,Yong Yang,Yelong Zheng,Rui Zhu
出处
期刊:Langmuir
[American Chemical Society]
日期:2022-07-14
卷期号:38 (29): 8854-8861
被引量:3
标识
DOI:10.1021/acs.langmuir.2c00974
摘要
Understanding the high water adhesion of rose petals is of great significance in artificial surface design. With all-atom molecular dynamics simulation, the wettability of nanoscale wrinkles was explored and compared to that of nanoscale strips with favorable hydrophobicity. The dewetting and wetting of gaps between nanoscale structures represent the Cassie-Baxter (CB) and Wenzel (WZ) states of the macroscopic droplet deposited on the textured surface, respectively. We uncovered the intermediate state, which is different from the CB and WZ states for wrinkles. Structures and free-energy profiles of metastable and transition states under various pressures were also investigated. Moreover, free-energy barriers for the (de)wetting transitions were quantified. On this basis, the roles of pressure and the unique structures of nanoscale wrinkles in the high water adhesion of rose petals were identified.
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