Constructing a composite lithium anode for high-performance solid-state lithium–metal batteries via in-situ alloying reaction

Solid-state lithium–metal batteries (SSLMBs) with ceramic Li[Formula: see text]La 3 Zr[Formula: see text]Ta[Formula: see text]O[Formula: see text] (LLZTO) electrolytes are widely deemed to be a viable candidate for high-energy storage devices with attractive safety. However, inadequate contact, dramatical volume variation and dendrite growth severally impede their practical applications. Herein, a composite Li metal anode consisting of LiF and CaLi 2 alloy is constructed by in-situ alloying reaction of Li and minute amount of CaF 2 . The as-formed CaLi 2 alloy and LiF in the composite Li metal anode not only improve the wettability of molten lithium to LLZTO by decreasing the surface tension, but also achieve the intimate contact and avoid anode volume collapse. The interfacial resistance is successfully decreased from 405.9 to 12.9 [Formula: see text] cm 2 by adopting the composite Li as electrodes. The symmetric cells can cycle at 0.1 mA cm[Formula: see text] for 1000 h, and cycle at 0.2 mA cm[Formula: see text] for 580 h. In addition, SSLMB by using LiFePO 4 (LFP) as the cathode exhibits a capacity retention of 70.9% after 125 cycles at 0.3 C as well as good rate performance. This work puts forward a rational and economic strategy to pave the path for the advance of SSLMBs.