甲醇
丙烷
电解
甲烷
催化作用
化学
丙醇
无机化学
电极
乙烯
有机化学
电解质
物理化学
作者
Jung Hyun Kim,Hong Sik Lee,Jung Tak Park
出处
期刊:Hwahag gonghag
[The Korean Institute of Chemical Engineers]
日期:2014-04-01
标识
DOI:10.9713/kcer.2014.52.2.247
摘要
powder with the perovskite structure was prepared as electrode catalyst using citrate method. Porous electrode was made with as-prepared catalyst, carbon as supporter and polytetrafluoroethylene (PTFE) as hydrophobic binder. As results of potentiostatic electrolysis with potential of -1.5~-2.5 V vs. Ag/AgCl in 0.1, 0.5 and 1.0 M KOH at 5 and on the porous electrode, liquid products were methanol, ethanol, 2-propanol and 1, 2-butanol regardless reaction temperature, while gas products were methane, ethane and ethylene at , and methane, ethane and propane at respectively. Optimal potentials for reduction in the view of over all faradic efficiency were high values (-2.0 and -2.2 V) for gas products whereas low potential (-1.5 V) for liquid products regardless of concentration and temperature.
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