丙烯醛
甘油
催化作用
吡啶
选择性
解吸
热脱附光谱法
吸附
化学
脱水
无机化学
吸附
核化学
有机化学
生物化学
作者
V.R. Chary Komandur,Satyanarayana Yedla,Putrakumar Balla,Balaga Viswanadham,Ramu Kuna,Umesh Kumar Utkoor
出处
期刊:Catalysis in green chemistry and engineering
[Begell House Inc.]
日期:2022-01-01
卷期号:5 (2): 19-30
标识
DOI:10.1615/catalgreenchemeng.2022043642
摘要
investigatedusing X-ray diffraction and N2 sorption. The acidic properties were investigated by the ex-situ FT-IR spectroscopy of pyridine adsorption and temperature programmed desorption (TPD) of ammonia. The dehydration reaction of glycerol was studied in the gas phase at temperature 320 ºC. Among several catalysts examined the niobium-supported SBA-15 catalyst with 30 wt.% of Nb2O5-SBA-15 exhibited higher activity of glycerol conversion (85%) and selectivity of acrolein (60%).
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