A Catellani and retro-Diels–Alder strategy to access 1-amino phenanthrenes via ortho- and interannular C–H activation of 2-iodobiphenyls

A palladium-catalyzed three-component domino reaction for the construction of 1-amino phenanthrene derivatives by ortho - and interannular C–H activation of 2-iodobiphenyls has been developed.