化学
戒指(化学)
热稳定性
氮气
起爆
盐酸
方位(导航)
组合化学
有机化学
爆炸物
地图学
酶
地理
作者
Wenhao Cui,Qi Liu,Ye Z,Ying He
出处
期刊:Organic Letters
[American Chemical Society]
日期:2023-07-20
卷期号:25 (30): 5661-5665
被引量:1
标识
DOI:10.1021/acs.orglett.3c02131
摘要
A series of bistetrazole-based energetic salts bearing a nitrogen-rich fused ring were designed and synthesized. Among them, compounds 4-10 showed good detonation properties and excellent thermostability. By treating nitrogen-rich fused ring 3 with concentrated hydrochloric acid, a new type of Dimroth rearrangement was observed that afforded compound 12 efficiently. This new transformation herein constitutes a valuable addition to the Dimroth rearrangement.
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