Boosting CO2 Electroreduction to Multi‐carbon Products via Oxygen‐rich Vacancies and Ce4+−O2−−Cu+ Structure in Cu/CeO2 for Stabilizing Cu+

Abstract Cu is a promising electrocatalyst for the CO 2 reduction reaction (CO 2 RR) to produce high‐value C 2+ products. Due to the fierce competition of the hydrogen evolution reaction, the slow diffusion of CO 2 , and the high energy barrier of the C−C coupling reaction, it is still challenging to achieve high activity and high selectivity to produce multi‐carbon products on copper‐based electrocatalysts. In this work, we synthesized Cu/CeO 2 catalysts with varying amounts of Cu doping, aiming at effectively converting CO 2 into C 2+ products through electroreduction. At a copper doping level of 9.77 wt%, the catalyst exhibited a current density of 16.8 mA cm −2 using a standard H‐type cell, achieving a C 2+ faradaic efficiency (FE) of 78.3 %. Through additional experiments and material characterization, we confirmed that controlling the Cu loading on the surface of CeO 2 is an effective way to regulate the ratio of Cu + to Cu 0 active sites and the number of oxygen vacancies. Furthermore, the strong electron interaction between Ce 4+ −O 2− −Cu + structure can stabilize Cu + species and enhance the overall stability of the catalyst. This strategy enhances the selectivity towards C 2+ products and effectively suppresses the competing hydrogen evolution reaction.