热固性聚合物
聚合物
玻璃化转变
氢键
高分子化学
模数
碳原子
刚度(电磁)
动态力学分析
化学
氢原子
材料科学
复合材料
分子
有机化学
烷基
作者
Benjamin Godwin,Monir H. Anvari,Tina Olfatbakhsh,Mahshid Mahbod,Abbas S. Milani,Gino A. DiLabio,Jeremy E. Wulff
出处
期刊:Macromolecules
[American Chemical Society]
日期:2023-02-08
卷期号:56 (4): 1592-1600
被引量:1
标识
DOI:10.1021/acs.macromol.2c02260
摘要
Chemical cross-links within polymers increase mechanical strength and rigidity. Such cross-links can be either irreversible (e.g., those derived from carbon–carbon bonds) or reversible (e.g., those that depend on X–H···O hydrogen bonds). Here we describe a ketone-functionalized derivative of polydicyclopentadiene that establishes an unprecedented network of vinyl C–H···O hydrogen bonds within the polymer. The resulting thermoset displays a significantly increased glass transition temperature relative to the unfunctionalized polymer, together with enhancements to storage modulus, Young’s modulus, and compression strength.
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