Interface reconstruction of MXene-Ti3C2 doped CeO2 nanorods for remarked photocatalytic ammonia synthesis

Prospective photocatalytic ammonia synthesis process has received more attentions but quite challenging with the low visible light utilization and weak N2 molecule absorption ability around the photocatalysts. Herein, interface reconstruction of MXene-Ti3C2/CeO2 composites with high-concentration active sites through the carbon-doped process are presented firstly, and obvious transition zones with the three-phase reaction interface are formed in the as-prepared catalysts. The optimal co-doped sample demonstrates an excellent photo response in the visible light region, the strongest chemisorption activity and the most active sites. Moreover, much more in-situ extra oxygen defects are also produced under light irradiation. It is expected that the double decorated catalyst shows a remarked ammonia production rate of above 0.76 mmol gcal−1·h−1 under visible-light illumination and a higher apparent quantum efficiency of 1.08 % at 420 nm, which is one of the most completive properties for the photocatalytic N2 fixation at present.