甲脒
钙钛矿(结构)
结晶度
热稳定性
碘化物
材料科学
相(物质)
羧酸盐
化学
化学工程
无机化学
有机化学
结晶学
工程类
作者
Junjie He,Yanfang Chu,Yizhen Sun,Rui Zhang,Jing Li,Lei Zhao,Hongmei Zhao,Peng-Fei Liu,Li Song
出处
期刊:Solar RRL
[Wiley]
日期:2021-07-10
卷期号:5 (8)
被引量:8
标识
DOI:10.1002/solr.202100188
摘要
Hybrid inorganic−organic perovskites (HIOPs) have the widest absorption range and the highest power conversion efficiency. Among HIOPs, formamidinium lead iodide (FAPbI 3 ) has a wider absorption range and better thermal and light stability. Unfortunately, the photovoltaic active α‐phase of FAPbI 3 transforms into its δ‐phase within several hours in ambient environment. Although partly sublimation of FA + with smaller cations can stabilize α‐FAPbI 3 , the multication systems suffer cation segregation and phase separation in long‐term use. Herein, a crystal surface engineering strategy to stabilize α‐FAPbI3 is developed. It is found that even introducing 1 mol% carboxylate anion can drastically improve the phase stability and operational stability of α‐FAPbI 3 in the ambient environment (r.h. 50%, 25 °C). After 1 month of exposure to air, the phase change of α‐FAPbI 3 is negligible. A detailed study indicates that the introduction of carboxylate anions prevents the water corroding the crystal surface and relaxes the strain in the crystals by increasing orientation diversity. The improved operational stability of the HIOPs arises from the intrinsic stability of pure formamidinium recipe and the stronger hydrogen bond between formamidinium and carboxylate. It not only provides a perovskite material for high‐performance solar cells, but also deepens the understanding of the phase stability of HIOPs.
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