沥青质
离聚物
分散剂
苯乙烯
聚苯乙烯
色散(光学)
甲基丙烯酸酯
高分子化学
化学
离子键合
化学工程
材料科学
有机化学
离子
复合材料
共聚物
聚合物
工程类
物理
光学
作者
Myung Guen Jo,Joon‐Seop Kim,Young‐Wun Kim
出处
期刊:Energy & Fuels
[American Chemical Society]
日期:2021-11-12
卷期号:35 (23): 19351-19361
被引量:5
标识
DOI:10.1021/acs.energyfuels.1c02037
摘要
The purpose of this work was to investigate the effects of polystyrene-based acidic copolymers and ionomers on the dispersion of asphaltenes in heavy oil. In the first part of the work, we studied the effect of the addition of sulfonated polystyrene acidic copolymers (SSA) and Na-neutralized ionomers (SSNa) on asphaltene dispersion. It was found that the SSA copolymers and the low ion content SSNa ionomers did not show asphaltene dispersion enhancement. However, high ion content SSNa ionomers improved asphaltene dispersion. In the second part of the work, styrene–methacrylate ionomers (SMANa) were used as dispersants. It was observed that the SMANa ionomers improved asphaltene dispersion significantly as the ion content increased and the molecular weight of the SMANa ionomer decreased. Finally, it was found that asphaltene dispersion was more effective when SMANa ionomers were used as asphaltene dispersants, compared to SSNa ionomers. Therefore, it can be concluded that to improve asphaltene dispersion, the acidic copolymers must first be converted to ionomers by neutralization. In addition, when using the ionomer as an asphaltene dispersant, it should be noted that the type of ionic group of the ionomer was more important to control asphaltene dispersion than the MW of the ionomer.
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