Torsional Strain Enabled Ring‐Opening Polymerization towards Axially Chiral Semiaromatic Polyesters with Chemical Recyclability

>100 °C). Intriguingly, mixing these complementary enantiopure polymers containing axial chirality promoted a transformation from amorphous to crystalline material, affording a semicrystalline stereocomplex with a melting transition temperature more than 300 °C. P(Me-DBO) were capable of depolymerizing back to Me-DBO in high efficiency, highlighting an excellent recyclability.