Controlled Synthesis and Growth Mechanism of Two-Dimensional Zinc Oxide by Surfactant-Assisted Ion-Layer Epitaxy

成核 溶解 扫描电子显微镜 材料科学 化学工程 离子 肺表面活性物质 X射线光电子能谱 分析化学(期刊) 纳米技术 化学 色谱法 有机化学 复合材料 工程类 冶金
作者
Chunfeng Huang,Qi Sun,Zhiling Chen,Dongping Wen,Zongqian Tan,Yaxian Lu,Yuelan He,Ping Chen
出处
期刊:Crystals [Multidisciplinary Digital Publishing Institute]
卷期号:13 (1): 5-5 被引量:3
标识
DOI:10.3390/cryst13010005
摘要

Two-dimensional (2D) zinc oxide (ZnO) has attracted much attention for its potential applications in electronics, optoelectronics, ultraviolet photodetectors, and resistive sensors. However, little attention has been focused on the growth mechanism, which is highly desired for practical applications. In this paper, the growth mechanism of 2D ZnO by surfactant-assisted ion-layer epitaxy (SA-ILE) is explored by controlling the amounts of surfactant, temperature, precursor concentration, and growth time. It is found that the location and the number of nucleation sites at the initial stages are restricted by the surfactant, which absorbs Zn2+ ions via electrostatic attraction at the water-air interface. Then, the growth of 2D ZnO is administered by the temperature, precursors, and growth time. In other words, the temperature is connected with the diffusion of solute ions and the number of nucleation sites. The concentration of precursors determines the solute ions in solution, which plays a dominant role in the growth rate of 2D ZnO, while growth time affects the nucleation, growth, and dissolution processes of ZnO. However, if the above criteria are exceeded, the nucleation sites significantly increase, resulting in multiple 2D ZnO with tiny size and multilayers. By optimizing the above parameters, 2D ZnO nanosheets with a size as large as 20 μm are achieved with 10 × 10−5 of the ratio of sodium oleyl sulfate to Zn2+, 70 °C, 50 mM of precursor concentration, and 50 min of growth time. 2D ZnO sheets, are confirmed by scanning electron microscope (SEM), energy-dispersive X-ray spectrometer (EDS), X-ray photoelectron spectroscopy (XPS), and Raman spectrum. Our work might guide the development of SA-ILE and pave the platform for practical applications of 2D ZnO on photodetectors, sensors, and resistive switching devices.

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