Quantum Tunneling of Photogenerated Charges for Artificial Photosynthesis

) of 13.6% was achieved for the photosynthetic reaction. This work offers guidance for designing novel, high-performance photocatalysts and photoelectrodes and lays the foundation for producing solar fuels at a large scale. Finally, the challenges and outlook for quantum tunneling-based artificial photosynthesis are discussed. Bidirectional tunneling-enhanced artificial leaf technology is expected to facilitate the development of efficient and durable artificial photosystems capable of converting solar energy to fuels and chemicals.