环加成
离子液体
催化作用
接受者
离子键合
光化学
材料科学
金属
化学
有机化学
离子
凝聚态物理
物理
作者
Fang Xu,Li Yang,Zhenwen Dai,Die Cong,Daoyuan Zheng,Tie Yu,Runqi Tu,Shengliang Zhai,Jing Yang,Fengling Song,Hao Wu,Wei Deng,C. Liu
标识
DOI:10.1002/advs.202206687
摘要
Abstract CO 2 cycloaddition with epoxides is a key catalytic procedure for CO 2 utilization. Several metal‐based catalysts with cocatalysts are developed for photo‐driven CO 2 cycloaddition, while facing difficulties in product purification and continuous reaction. Here, poly(ionic liquid)s are proposed as metal‐free catalysts for photo‐driven CO 2 cycloaddition without cocatalysts. A series of poly(ionic liquid)s with donor–acceptor segments are fabricated and their photo‐driven catalytic performance (conversion rate of 83.5% for glycidyl phenyl ether) outstrips (≈4.9 times) their thermal‐driven catalytic performance (17.2%) at the same temperature. Mechanism studies confirm that photo‐induced charge separation is promoted by the donor–acceptor segments and can accelerate the CO 2 cycloaddition reaction. This work paves the way for the further use of poly(ionic liquid)s as catalysts in photo‐driven CO 2 cycloaddition.
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