蒙脱石
插层(化学)
材料科学
流变学
沥青
紫外线
动态剪切流变仪
傅里叶变换红外光谱
复合材料
化学工程
化学
流变仪
有机化学
光电子学
工程类
作者
Fengjie Cai,Zheng Feng,Wenjie Song,Fei Liu,Qi Chen,Zhuang Wang,Linhao Zhang
出处
期刊:Journal of Materials in Civil Engineering
[American Society of Civil Engineers]
日期:2024-02-01
卷期号:36 (2)
标识
DOI:10.1061/jmcee7.mteng-16735
摘要
In order to improve the thermo-oxidative and ultraviolet (UV) aging resistance of bitumen, ultraviolet absorber (UVA) was intercalated into organo-montmorillonite (OMMT) and ultraviolet absorber-intercalated organo-montmorillonite (UVA/OMMT) was used to modify bitumen. Four kinds of UVA/OMMT, including UV326/OMMT, UV328/OMMT, UV531/OMMT, and UV770/OMMT, were prepared by organic intercalation of OMMT with different UVAs (UV326, UV328, UV531, and UV770). X-ray diffraction testing was used to evaluate the intercalation effect of UVA/OMMT. UVA/OMMT-modified bitumen was prepared by melt blending of the base bitumen with different UVA/OMMTs. Then, thin film oven testing and ultraviolet aging testing were carried out on the UVA/OMMT-modified bitumen. The effects of UVA/OMMT on rheological properties, generic fractions, and functional groups of bitumen before and after thermo-oxidative and ultraviolet aging were studied by dynamic shear rheometer testing, thin-layer chromatography with flame ionization detection, and Fourier transform infrared spectroscopy, respectively. Based on these, the thermo-oxidative and UV aging resistance of different UVA/OMMT-modified bitumens were evaluated based on the rheological and chemical indexes. Results show that UV326/OMMT and UV328/OMMT have better effects on the thermo-oxidative aging and UV aging resistance of bitumen than OMMT, while the UV531/OMMT and UV770/OMMT exhibit worse effects on the thermo-oxidative aging and UV aging resistance of bitumen than OMMT, which is related to the better intercalation effects of UV326/OMMT and UV328/OMMT, and the poor intercalation effects of UV531/OMMT and UV770/OMMT.
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